In this paper, we define partial orders (POs) of polar codes based on the Bhattacharyya parameter and the bit-error probability, respectively. These POs are applicable to arbitrary binary memoryless symmetric channel (BMSC). Leveraging the extreme inequalities of polarization transformation, we derive new POs in BMSC based on the corresponding POs observed in the Binary Erasure Channel (BEC). We provide examples that demonstrate the inability of existing POs to deduce these novel POs. Furthermore, we establish upper bounds for the expansion parameter $\beta$ if the polar codes constructed by $\beta$-expansion method obey these POs.